Theory of chemical bonds in metalloenzymes XXIII fundamental principles for the photo-induced water oxidation in oxygen evolving complex of photosystem II

K. Yamaguchi^a,b,c,d,e*, S. Yamanaka^b,e, H. Isobe^f, M. Shoji^g, K. Miyagawa^a, T. Kawakami^b,c

a The Institute for Scientific and Industrial Research, Osaka University, Osaka, 567-0047, Japan

b Graduate School of Science, Osaka University, Toyonaka, 560-0043, Japan

c RIKEN Center for Computational Science, Kobe, Hyogo, 650-0047, Japan

d Institute for Nanoscience Design, Osaka University, Toyonaka, Osaka, 560-8531, Japan

e Division of Quantum Information and Quantum Biology (QIQB), Osaka University, Toyonaka, 560-0043, Japan

f Graduate School of Natural Science and Technology, Okayama University, Okayama, 700-8530, Japan

g Center of Computational Sciences, Tsukuba University, Tsukuba, Ibaraki 305-8577, Japan